Just Accepted
Just Accepted
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ArticleDirect synthesis of highly porous Cr-MOFs with hexatopic car-boxylate ligands for water adsorptionChaozhuang Xue, Yingying Zhang, Konggang Qu, Shuwen Gong, Huajun Yang*
Chromium(III) MOFs; Rigid-acs based pacs; Highly porous; Stable MOFs; Water adsorption
ABSTRACT
Novel pacs-type chromium(III) metal-organic frameworks with highly porosity and structural stability are obtained via a one-pot dual-modulator synthetic strategy. These Cr-pacs can be viewed as the partitioned structures of rigid acs frameworks, with the consideration of both size and symmetry matching between acs forming ligand (hexatopic carboxylate ligand) and partitioning ligand (tridentate pyridine ligand). -
Reviewg-C3N4-based S-scheme heterojunction photocatalyst and its applicationZhiwei Meng, Shasha Chen, Pingyu Yang, Yupeng Yan, Guanjie Jiang, Qin Zhang, Yang Li*
S-scheme heterojunctions; Carbon nitride (g-C3N4); Environmental application; Photocatalysis
ABSTRACT
Theoretical Basis and Application Scenarios of g-C3N4-Based S-scheme Heterojunction Photocatalysts -
ArticlePhotosynthesis of CH4 and H2O2 from CO2 and H2O over Pd/SnNb2O6 via strong metal-support interactionJiaxin Zhang1, Yingzhang Shi1, Zhiwen Wang*, Yujie Song*, Dongpeng Yan*
Photocatalysis; CO2 Reduction; H2O oxidization; Metal-support interaction
ABSTRACT
Pd/SnNb2O2?nanosheets efficiently convert CO2?and H2O into CH4?and H2O2?through strong metal–support interactions, without any sacrificial agents. -
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ArticleEfficient charge separation of RF/CdTMT S-scheme photocatalyst with enhanced photocatalytic H2O2 productionYonghui Ma, Lei Ji*, Jinfeng Zhang*, Graham Dawson, Kai Dai*
S-scheme heterojunction; Photocatalytic H2O2 production; RF; CdTMT; Charge separation
ABSTRACT
RF/CdTMT S-scheme heterojunctions synthesized by an oil bath method facilitate charge separation, showing 15.15 and 3.01 times higher H2O2?yields than the pristine catalysts. -
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ArticleUnveiling the interfacial charge dynamics in organic/inorganic C3N4/Bi2O3 S-scheme heterojunction for efficient solar-driven H2O2 synthesisJiaming Li, Yuxin Huang, Chengshan Zhao, and Kai Wang*
H2O2 production; Heterojunction photocatalyst; Interfacial charge transfer; S?scheme mechanism
ABSTRACT
An efficient coupling strategy of unique carrier migration pathways and superior carrier separation efficiencies of S-scheme organic/inorganic C3N4/Bi2O3?heterojunctions are developed for solar-driven H2O2?synthesis. -
ArticleFast hydrogenolytic debenzylation enabled by hierarchically ordered porosity and accessibly rich Pd(0) sitesZhe Li, Gui-Long Wang, Xin Feng, Jia-Hui Guo, Lu Bai, Jie Chen*, and Ming-Shui Yao*
Hydrogenolytic debenzylation; Hierarchically ordered porous structure; Bimetallic catalysts; PdNi nanocatalyst
ABSTRACT
Hydrogenolytic debenzylation is vital for restoring the activity of protected functional groups. This study uses a PdNi/DOM-NC catalyst with a hierarchically ordered porous structure to rapidly and efficiently deprotect TADBIW with a 97.30% yield, achieving excellent performance at low Pd loadings. -
ArticleLocalized Co3O4/In2S3 S-scheme heterojunction by polarization engineering for achieving an exceptional H2 efficiencyMengru, Qu, Chuanzhi Sun, Shujuan Jiang*, and Shaoqing Song*
Surface polarization; Catalytic facet activation; S-scheme mechanism; Photocatalytic water splitting; Reaction kinetics
ABSTRACT
Surface polarization engineering on Co3O4/In2S3?S-scheme heterojunction enhances the charge migration and activity of redox facets, achieving 1.32% solar-to-H2?efficiency through the improved chemisorption to *H and *OH. -
ArticleRapid and stable degradation of dichlorvos on chili pepper and histamine in sardines using S-scheme Al6Si2O13/g-C3N4 nanocompositesAoyun Meng, Zhenhua Li, Guoyuan Xiong, Zhen Li *, and Jinfeng Zhang*
Food safety; Controlling; Contaminants; Nanocomposites; S-scheme
ABSTRACT
S-scheme Al6Si2O13/g-C3N4?photocatalyst enhances charge separation for efficient degradation of dichlorvos on chili peppers and histamine in sardines under light irradiation. -
ArticleManganese valence modulation in ZnGa2O4 via simultaneously localized charge accumulation and oxygen vacancy engineering controlled by Li+ and F- substitutions for tailored applicationsC. X. Chen, W. Y. Li, C. Y. Ni, W. B. Dai*
ZnGa2O4; Valence modulation; Mn; Lattice site engineering; Multimodal PL
ABSTRACT
The table of contents entry: Li+/F-?co-doping enables precise Mn2+/Mn4+?ratio control in ZnGa2O4?via localized charge accumulation and oxygen vacancy repair, leading to color-tunable dual-mode luminescence for tailored applications. -
ReviewQuasi-one-dimensional antimony selenide photocathodes: From fundamentals to future directionZiying Zhang, Xiangjiu Guan*, and Liejin Guo*
Antimony selenide; Quasi-one-dimensional; Photoelectrochemistry; Interface engineering; Solar-to-fuel
ABSTRACT
Future research on Sb2Se3-based photocathodes should focus on co-catalyst design, interface engineering, controlling the crystal quality and defect states of the absorber, exploring alternative reactions beyond HER, and developing novel protection strategies to enhance stability. -
ArticleTuning the d-band center of amorphous NiCo alloy via P doping for enhanced urea electrolysisWenjie Jiang, Jiali Lu, Jia Wu, Boyao Feng, Zhixiang Zhai, Huan Wen, and Shibin Yin*
Phosphorus doping; Amorphous NiCo alloy; Reactant adsorption; Urea oxidation reaction; Hydrogen evolution reaction
ABSTRACT
Phosphorus doping induces?d-band upshift in amorphous NiCo to balance reactant adsorption, thereby promoting urea oxidation and accelerating water dissociation. -
ArticleConstructing trimetallic catalyst via sequential ion-exchange for enhanced ampere-level water oxidationDequan Li, Shanshan Fan, Wenjing Liu, Zhonge Luo, Mingpeng Chen*, Congcong Shen, Wangwei Liao, Bo Li, Mao Zhang, Yuewen, Wu, Boxue Wang, Feng Liu, Huachuan Sun, Tong Zhou, and Qingju Liu*
Trimetallic catalyst; Ion-exchange; Oxygen evolution reaction; Ampere-level current density; Synergistic effect
ABSTRACT
Fe-doped NiCoO2?was synthesized via a simple sequential ion-exchange strategy, in which the hierarchical nanosheet architecture and the synergistic interactions among multiple metal species collectively enable highly efficient and stable oxygen evolution during water electrolysis. -
ArticleSuper internal electrostatic field effect on self-powered X-ray detector in ferroelectric Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystalFuai Hu, Yanru Yin*, Yang Li, Feifei Guo, Jianhui Liu, and Zeliang Gao*
ABSTRACT
Pioneering PMN-PT piezoelectric single crystals for self-powered X-ray detection. Achieves high sensitivity (346 μC Gyair-1?cm-2) and ultralow detection limit (0.43 nGyair?s-1) at 40 keV, surpassing commercial?α-Se detector (20 μC Gyair-1?cm-2, 5500 nGyair?s-1). Demonstrates heavy-metal ferroelectric crystals as ideal platforms for high-performance radiation detectors. -
ArticleA stable Zr-MOF with trap-and-flow channels for efficient natural gas purificationZhenyu Ji, Yucheng Xiao, Yunzhe Zhou, Ting Zhao, Lingna Yang, Cheng Chen, Mingyan Wu*, and Maochun Hong
ABSTRACT
A stable Zr-MOF with trap-and-flow channels can realize efficient natural gas purification from ternary mixture, in which the larger channels facilitate rapid gas diffusion and smaller pores enable efficient gas adsorption. -
ArticleOxophilic support mediated interfacial water reconstruction on RuO2 for high-efficiency proton exchange membrane electrolysisJuan Zhu1, Jingxiang Xia1, and Wei Luo*
Acidic oxygen evolution reaction; Interfacial H2O; Hydrogen-bond network; Proton exchange membrane water electrolyzer
ABSTRACT
We demonstrated that anchoring RuO2?onto oxophilic MoO3?nanosheet promotes the connectivity of hydrogen-bond network and induces the ordered arrangement of interfacial water molecules in the electrical double layer. These water molecules serve as efficient proton-transfer mediators, accelerate the deprotonation step, facilitate rapid proton hopping, thereby leading to both enhanced catalytic activity and stability toward acidic water oxidation. -
News & ViewsSynergistic integration of metal-organic frameworks and covalent organic frameworks in structural chemistryLijuan Feng, Liangliang Zhang*, and Yu Fang*
Halide solid electrolytes; Electrochemical stability; Interfacial engineering; Manufacturing evaluation; All-solid?state lithium batteries
ABSTRACT
This review summarizes key advances in halide solid-state electrolytes, from material design to industrial scale-up, and outlines the path toward achieving stable, high-performance batteries. -
ArticleModulating charge kinetics in CDs/CTF S-scheme hybrids for enhanced H?O? photosynthesisHaoyuan Qin, Lijing Wang, Yuanhao Tang, Weilong Shi*, Changyu Lu*
Covalent triazine frameworks; N, S-CDs; S-scheme heterojunction; H2O2; photocatalysis
ABSTRACT
The constructed N,S-CDs/CTFs S-scheme heterojunction utilizes synergistic conjugation and an internal electric field to enhance electron transfer, achieving 1.7-fold superior antibacterial activity via H2O2?production. -
ReviewMultiscale interfacial engineering of halide electrolytes for high-performance all-solid-state lithium batteriesJialiang Zhu, Yuan Zhong, Bingqing Xu*, and Gen Zhang*
ABSTRACT
This review summarizes key advances in halide solid-state electrolytes, from material design to industrial scale-up, and outlines the path toward achieving stable, high-performance batteries. -
ArticleSub-nanoscale oxygen-defect-rich MoO3-x: A versatile platform for label-free ultrasensitive SERS biodetectionXiaoyu Song1, Xinghua Liu1, Lei Xu1, Aochi Liu, Xiangyu Meng, Yuening Wang, Mingjian Zhang, Guangcheng Xi*, Jie Lin*, Xiaotian Wang*, Gengchen Xie*
ABSTRACT
MoO3-x?sub-nanowires with oxygen-defect-rich were synthesized. These MoO3-x?Sub-NWs SERS substrates exhibit ultrasensitive, label-free detection of environmental pollutants and enable highly accurate cancer cell classification. -
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Short CommunicationNa2(C6H4NO3)2?H2O: A promising ultraviolet nonlinear optical crystal with strong second-harmonic generation effect and large birefringenceXuan Pang, Yongzhang Wang, Chunmei Huang*
ABSTRACT
A novel NLO crystal, Na2(C6H4NO3)2?H2O, composed of Na+?cations and planar organic anions [C6H4NO3]–, exhibits a short UV cutoff edge below 282 nm, a strong SHG response (～6.2× KDP), and a large birefringence (0.394 at 546.1 nm). -
ArticleUnconventional configuration of excimer in luminescent aggregates uncovered by in situ photo-difference electron densityLong-Qi Yang, Xiao-Ming Jiang*, Fa-Kun Zheng, Guo-Cong Guo*
Luminescent aggregates; Excimer; In-situ electron density; Noncovalent interactions; Light-induced structural evolution
ABSTRACT
Our experiment enables direct observation of pyrene excimer formation, identifying a unique T-shaped configuration that revises the conventional understanding of their molecular arrangement. -
ArticleFrom laboratory insights to industrial applications in continuous flow sonophotocatalytic abatement of persistent pollutants enabled by a broad-spectrum S-scheme photocatalystRajamani Manju, Ganesh Masilamani, Bernaurdshaw Neppolian*
Tetracycline; Zeolitic imidazole framework; Cobalt tungstate; Sonophotocatalytic degradation; Wastewater remediation; Continuous-flow reactor; S-scheme heterojunction.
ABSTRACT
A broad-spectrum S-scheme photocatalyst enables efficient sonophotocatalytic degradation of pharmaceutical pollutants and performs reliably in a continuous-flow system for practical wastewater treatment
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